Osaka Electro-Communication University Faculty Information Database >外山　真理

Department of Engineering Science

外山　真理　TOYAMA Mari 画像の説明

  • Department
    工学部　基礎理工学科　特任講師
  • Specialized field
    錯体化学・光化学・基礎化学・分析化学
  • Research theme
    新規ポリピリジル-ルテニウム(II)錯体の精密構築
    光増感ルテニウム(II)色素錯体の合成
    光触媒
    ポリピリジル-コバルト(III)錯体の合成
    錯体を使ったフッ化物イオンの検出剤の開発
  • URL
  • Career
    • Educational background
      明治大学　理工学部　工業化学科　卒業（1999)
      明治大学大学院　理工学研究科　工業化学専攻　博士前期課程　修了（2001)
      明治大学大学院　理工学研究科　応用科学専攻　博士後期課程　修了（2007)
    • Work history
      明治大学 理工学部 兼任講師（2007.4-2015.3)
      駒澤大学 医療健康科学部 診療放射線技術学科 非常勤講師（2008.4-2015.3)
      青山学院大学 理工学部 非常勤講師（2010.10-2012.9)
      甲南大学 理工学部 機能分子化学科 任期付き助教（2015.4-2019.3)
      大阪府立大学工業高等専門学校 総合工学システム学科 環境物質化学コース 期限付き講師（2019.4-2020.3）
      大阪電気通信大学 工学部 基礎理工学科 特任講師（2020.4-）
  • Degree, etc.
    博士(工学)　明治大学 2007年
  • Awards, etc.
  1. 21st ICP Satellite Symposium on Photochemical and Photobiology of Complexes Including Supramolecular Systems and Coordination Compounds　学生ポスター賞（Europe Prize）(2003.8)
  2. 第55回錯体化学会　学生ポスター賞(2005.9)
  • Academic societies
    錯体化学会
    日本化学会
    複合系の光機能研究会

外山　真理　TOYAMA Mari

  • Department
    工学部　基礎理工学科　特任講師
  • Department / Faculty Management


  • Activities within the university, such as committees, centers, and research institutes


  • Collaboration activities with industry, government, and academia


  • External activities
  • Other

外山　真理　TOYAMA Mari

  • Department
    工学部　基礎理工学科　特任講師
  • Undergraduate education (lectures)
    化学２
    物理化学１
    無機化学
    化学実験
    プロジェクト活動スキル入門
    基礎理工学入門
  • Graduate education (lecture)


  • Teaching thesis
    • 卒業論文等の指導
  1. 三脚型配位子トリ-(2-ピリジル)アミンとピコリンアミドを持つ Ru(II)錯体の合成と構造, 伊藤智恵理, 学士（理工学），甲南大学（2015).
  2. ビス(ジ-2-ピリジルアミン)ピコリネートルテニウム(II)錯体の合成と構造と光化学反応, 三島太地，学士（理工学），甲南大学（2015).
  3. 2,2'-ビピリジンとアセチルアセトナトを1 つずつ持つルテニウム(II)錯体の合成と結晶構造～trans(O,S)-[Ru(bpy)(dmso-O)2(dmso-S)2](OTf)2を原料としたcis 型ビス-ヘテロレプティック錯体の合成法の検討～，藤本大地，学士（理工学），甲南大学（2015）.
  4. ビス(2,2'-ビピリジン)ルテニウム(II)錯体の新規合成法の検討，高山美咲，学士（理工学），甲南大学（2015).
  5. トリピリジルジアミンを2つ持つRu(II)錯体の合成法と光アネーション反応の検討，後藤良俊, 学士（理工学），甲南大学（2015).
  6. 銀イオン捕集能を有するチオエーテル鎖を持つトリスヘテロレプティック Ru(II)錯体の合成と構造, 磯野拓実，学士（理工学），甲南大学(2016).
  7. ピコリンアミドが配位したビス(2,2’-ビピリジン)Ru(II)錯体の合成と水素結合能に関する調査，遠藤美佳，学士（理工学），甲南大学（2016).
  8. カルボニル基を有する 2,2’-ビピリジル配位子を1つ持つ Ru(II)混合配位子錯体の合成と構造とそれらの発光挙動，川上佑介，学士（理工学），甲南大学（2016).
  9. ビス(2,2'-ビピリジン)ピコリネート Ru(II)錯体の合成とその構造における対イオンの影響，中安俊文，学士（理工学），甲南大学（2016).
  10. トリスヘテロレプティック Ru(II)錯体の合成とその光化学的な挙動における置換基効果，松岡優実，学士（理工学），甲南大学（2016).
  11. 4,4'-ビス(クロロメチル)-2,2’-ビピリジンを有するRu(II)錯体のCl基の光脱離反応，朝野裕樹，学士（理工学），甲南大学（2017).
  12. 二酸化チタンに吸着するカルボニル基を持つ Ru(II)錯体の合成，尾本沙奈香，学士（理工学），甲南大学（2017).
  13. 2,2'-ビピリジンとアセチルアセトナートを持つtrans型Ru(II)錯体の合成と単座配位子の置換反応，田中志保，学士（理工学），甲南大学（2017).
  14. ピコリンアミドが配位したビス(2,2'-ビピリジン)Ru(II)錯体による陰イオン検出に関する調査，藤井悠大，学士（理工学），甲南大学（2017).
  15. クラス b 金属イオンの選択的回収可能なアザチオエーテル鎖を持つ光触媒合成の条件検討，永柄 慶輔，学士（理工学），甲南大学（2018）.
  16. フッ化物イオンの目視での検出と再生が可能なルテニウム(II)錯体の改良，長谷川 僚己，学士（理工学），甲南大学（2018).
  17. CH2Cl基を持つ 2,2'-ビピリジンを有するビス型混合配位子錯体の合成，中野拓心，学士（理工学），甲南大学（2018).
  18. ジ-2-ピリジルアミンが配位したCo(Ⅲ)によるフッ化物イオン検出に関する調査，山本優，学士（理工学），甲南大学（2018).
  19. コバルト(III)イオンと糖（ガラクツロン酸）の錯形成反応に関する研究，吉本 卓矢，学士（理工学），甲南大学（2018).
  • 指導学生の受賞
  1. 中野拓心，光機能性錯体の構築法の検討，甲南大学 リサーチフェスタ2018，審査員特別賞（2018).
  2. 山本優，安価なコバルト(Ⅲ)錯体を用いた目視でわかるフッ化物イオンの検出剤の開発，甲南大学 リサーチフェスタ2018，アトラクティブプレゼンテーション賞（2018).
  • Teaching portfolio
  • Posture for class
    学生の理解度を確認しながら授業を進めます．学生が自修をしやすい授業資料の配布や板書を意識し，学生の自主的な学習を促すよう工夫します．
  • Self-evaluation of educational activities
    化学を専門としない学生には，日常生活と化学のリンクを意識し，化学への興味を持ってもらう工夫からしています．化学を専門とする学生には，高校化学より一歩進んだ知識を，自分の言葉で専門用語を使って説明するトレーニングを意識的にしてもらいます．
  • Training activities to improve classes
    最新の専門的な知見をもとに授業をできるよう，かつ，社会のニーズに対応できるよう，国内外の学会等に積極的に参加し，情報収集をしています．
  • Active learning
    学生が，学内外の人とコミュニケーションをとる機会をできるだけ設けるようにしています
  • Outline of main course subjects and achievement targets
  • Level of achievement against specific goals
  • Responding to requests from students
    学生アンケートや課題のコメント欄の内容を，授業にフィードバックするようにしています．

外山　真理　TOYAMA Mari

  • Department
    工学部　基礎理工学科　特任講師
  • Books etc.
  • Academic papers, works, etc.
  1. "Syntheses and Crystal Structures of Mono(2,2’-bipyridine)dichlorobis(dimethyl sulfoxide-S)ruthenium(II) Complexes, [RuCl2(bpy)(dmso-S)2], Mari Toyama, Ken-ichi Inoue, Shinobu Iwamatsu, and Noriharu Nagao, Bull. Chem. Soc. Jpn. Vol. 79, No. 10, 1525-1534 (2006)
  2. "Syntheses and Crystal Structures of Mono(di-2-pyridylamine)chloro(dimethyl sulfoxide-S)ruthenium(II) Complexes [RuCl2(Hdpa)(dmso-S)2] and [RuCl(Hdpa)(dmso-O)(dmso-S)2](OTf)", Mari Toyama, Ryuji Suganoya, Daisuke Tsuduura, and Noriharu Nagao, Bull. Chem. Soc. Jpn. Vol. 80, No. 5, 922-936 (2007) [Selected paper].
  3. "Syntheses, Crystal Structures, and Conversion of Three Linkage Isomers of Di-2-pyridyl Ketone in Dichlorobis(dimethyl sulfoxide-S)ruthenium(II) and Chlorobis(dimethyl sulfoxide-S)ruthenium(II) Complexes: [RuCl2(dpk-κ2N,O)(dmso-S)2], [RuCl2(dpk-κ2N,N’)(dmso-S)2], and [RuCl(dpk-OH-κ3N,O,N’)(dmso-S)2]",　Mari Toyama, Makito Nakahara, and Noriharu Nagao, Bull. Chem. Soc. Jpn. Vol. 80, No. 5, 937-950 (2007) [Selected paper].
  4. "Crystal Structures, and Substitution Reactions of trans(O,S)-[RuCl(bpy)(OH2)(dmso-S)2]+ and Three Derivative Complexes, trans(L,S)-[RuCl(bpy)(L)(dmso-S)2]+ (bpy: 2,2’-bipyridine, dmso: dimethyl sulfoxide, L = dmso-O, MeOH, or MeCN)", Mari Toyama, Shinobu Iwamatsu, Ken-ichi Inoue, and Noriharu Nagao, Bull. Chem. Soc. Jpn. Vol. 83, No. 12, 1518-1527 (2010).
  5. "Crystal Structure of Trans(Cl),cis(S)-dichlorobis(dimethyl sulfoxide-S)(N,N,N',N'-tetramethylethylendiamine)ruthenium(II)", Mari TOYAMA, Satoshi IWATSUKI, and Noriharu NAGAO, X-ray Structure Analysis Online 2016, VOL. 32, 25-26.
  6. "Coordination structure and extraction behavior of a silver ion with N-substituted-9-aza-3,6,12,15-tetrathiaheptadecanes: significant effect of Ph-C-N framework on the extractability", Satoshi Iwatsuki, Atushi Ichiyama, Syogo Tanooka, Mari Toyama, Kosuke Katagiri, Masatoshi Kawahata, Kentaro Yamaguchi, Hiroshi Danjo and Kenji Chayama, Dalton Trans., 2016, 45, 12548-12558.
  7. "Crystal Structure of (2-Picolinato)bis(2,2'-bipyridine)ruthenium(II) Chloride", Mari TOYAMA, Toshifumi NAKAYASU, and Noriharu NAGAO, X-ray Structure Analysis Online 2017, VOL. 33, 11-13.
  8. "Co-extraction and Concentration of Dyes into the Ionic Liquid Formed in an Aqueous Solution", Kenji CHAYAMA, Nobuhiko OOI, Jun KAWAMURA, Mari TOYAMA and Satoshi IWATSUKI, ISEC 2017 - The 21st International Solvent Extraction Conference, 20-27.
  9. "Crystal Structure of 9-Aza-3,6,12,15-tetrathiaheptadecane Hydrochloride", Mari Toyama, Takumi Isono, Atsushi Ichiyama, and Keiji Chayama, X-ray Structure Analysis Online, 2018, VOL. 34, 7-8.
  10. "Photochemical CO2 Reduction Catalyzed by Trans(Cl)-Ru(2,2'-bipyridine)(CO)2Cl2 Bearing Two Methyl Groups at 4,4'-, 5,5'- or 6,6'-Positions in the Ligand", Yusuke Kuramochi, Jun Itabashi, Mari Toyama, and Hitoshi Ishida, CHEMPHOTOCHEM, 2018, 2, 314-322.
  11. "C1-symmetrical cis-bis(di-2-pyridylamine)chloro(dimethyl sulfoxide-S)ruthenium(II) complex: Synthesis, crystal structure, and anion recognition using the NH groups in the chelating ligands", Mari Toyama, Daichi Mishima, Ryuji Suganoya, Noriharu Nagao, Inorganica Chimica Acta 478 (2018) 104-111.
  12. "Crystal Structure of cis-Bis(2,2'-bipyridyl)dichlorocobalt(III) Nitrate Methanol Solvate", Mari Toyama, X-ray Structure Analysis Online, 2018, VOL. 34, 41-43.
  13. "Mono(2,2'-bipyridyl)Ru(II) Complex with Four Dimethyl Sulfoxide Ligands as Precursor for cis-Bis-heteroleptic Ru(II) Complex; Syntheses, Structures, and Substitution Reaction", Mari TOYAMA, Daichi Fujimoto, Yumi Matsuoka, Yuki Asano, Noriharu Nagao, European Journal of Inorganic Chemistry, 2018, 39, 4349-4360.
  14. "Bis-heteroleptic Ruthenium(II) Complex with 2-Picolinamide: Synthesis, Crystal Structure, and Spectroscopic Study for Anion Recognition using Amide Group", Mari Toyama, Yudai Fujii, Mika Endo, Inorganica Chimica Acta 486 (2019) 304-313.
  15. "Crystal Structure of cis-Bis(2,2'-bipyridyl)bis(trifluoromethanesulfonate)cobalt(II)", Mari Toyama and Yu Yamamoto, X-ray Structure Analysis Online, 2019, VOL. 35, 21-23.
  16. "Crystal Structure of 6-Aza-3,9-dithiaundecane Hydrochloride", Mari Toyama and Kenji Chayama, X-ray Structure Analysis Online, 2019, VOL. 35, 55-56.
  17. "Syntheses and Characterization of a Pair of Isomers of Heteroleptic Bis(Bidentate) Ruthenium(II) Complexes with Two Different Monodentate Ligands ", Mari Toyama, Takako Takizawa, Itaru Morita, Noriharu Nagao, Yusuke Kuramochi, and Hitoshi Ishida, Chemistry - A European Journal, Volume 25, Issue 72, 16582-16590 [selected as Cover Picture].
  • Conference Activities & Talks
  1. "SYNTHESIS AND PHOTOCHEMICHAL REACTION OF [Ru(H2tpda)2]2+ and [Ru(Hdpa)3]2+ (H2tpda: TRI-2-PYRIDYLDIAMINE, Hdpa: DI-2-PYRIDYLAMINE)", Mari Toyama, Ryuji Suganoya, Noriharu Nagao, 34th International Conference on Coordination Chemistry in Edinburgh, UK (2000.7).
  2. "SYNTHESES AND PHOTOCHEMICAL REACTION OF MONO(TRIPYRIDYLDIAMINE)RUTHENIUM(II) COMPLEXES WITH ACETONITRILE LIGAND", Mari Toyama, Katsuhiro Hiramastu, Noriharu Nagao,
    35th International Conference on Coordination Chemistry in Heidelberg, Germany (2002.7).
  3. "SYNTHESES AND PHOTOCHEMICAL REACTIONS IN ACETONITRILE OF HETEROLEPTIC RUTHENIUM(II) COMPLEXES WITH TERPYRIDINE AND TRIPYRIDYLDIAMINE ANALOGUES ", Mari Toyama, Noriharu Nagao, 35th International Conference on Coordination Chemistry, in Heidelberg, Germany (2002.7).
  4. "Syntheses and Photochemical Reaction of Ruthenium(II) Complexes with Tri-2-pyridyamine", Mari Toyama, Hideaki Matsuda, Katsuhiro Hiramatsu, Noriharu Nagao, 21st ICP Satellite Symposium on Photochemical and Photobiology of Complexes Including Supramolecular Systems and Coordination Compounds (草津) [ポスター賞受賞] (2003.8).
  5. "Synthesis and Reactions of Ruthenium(II) Complexes with Di-2-pyridylamine and 2,2'-bipyridine in Trans Configuration", Mari Toyama, Gaku Tanaka, Atsushi Mizunoya, Ken-ichi Inoue, Noriharu Nagao, 36th International Conference on Coordination Chemistry in Merida, Mexico (2004.8).
  6. "Synthesis, Structures, and Linkage Isomerization of Mono(Di-2-Pyridyl ketone)Ruthenium(II) Complexes", Noriharu Nagao, Mari Toyama, Makito Nakahara, 36th International Conference on Coordination Chemistry, in Merida, Mexico (2004.8).
  7. "AXIAL LIGAND SUBSTITUTION IN MONO(2,2’-BIPYRIDINE)CHLOROBIS(DIMETHYL SULFOXIDE-S)RUTHENIUM(II) COMPLEXES", Mari Toyama, Shinobu Iwamatsu, Takashi Kushida, and Noriharu Nagao, 1st Asian Conference on Coordination Chemistry, 岡崎(2007.8).
  8. "PHOTOISOMERIZATION AND SUBSTITUTION REACTION MONO(1,3-DI(2-PYRIDYL)-1,3-PROPANDIONATE)RUTHENIUM(II) COMPLEX", Mari Toyama and Noriharu Nagao, 18th International Symposium on the Photochemistry and Photophysics of Coordination Compounds, 札幌(2009.7）.
  9. "SYNTHSES ANS STRUCTURES OF MONO(1,10-PHENANTHOROLINE)RUTHENIUM(II) COMPLEXES", Mari Toyama and Noriharu Nagao, 2st Asian Conference on Coordination Chemistry, 南京(2009.11）.
  10. "Syntheses and Crystal Structures of Ruthenium(II) Complexes with One (3-chloro-6-pyridazyl)(2-pyridyl)amine (Hcpdpa)", Mari Toyama , Tomokazu Ishida, and Noriharu Nagao, 39th International Conference on Coordination Chemistry, in Adelaide, Australia(2010.7).
  11. "Syntheses and Crystal Structure and Solution Chemistry of Ruthenium(II) Dimethyl Sulfoxide Complexes with Methylamine. [RuCl2(NH2Me)2(dmso-S)2], [RuCl2(NH2Me)(dmso-S)3], and [RuCl2(NH2Me)(CH3CN)(dmso-S)2] ", Mari Toyama , Takashi Kushida, and Noriharu Nagao, 39th International Conference on Coordination Chemistry, in Adelaide, Australia (2010.7).
  12. "Syntheses and Structures of Ru(II)-dmso Complexes with a Di-2-pyridylamine and a Methylamine Derivative", Mari Toyama , Takashi Kushida, and Noriharu Nagao, 3rd Asian Conference on Coordination Chemistry, in New Delhi, India (2011.10).
  13. "Syntheses and Characterization of Ru(II)-dmso Complexes with a Picolinate Ligand", Mari TOYAMA, Nobuyoshi TANAKA, and Noriharu NAGAO, 40th International Conference on Coordination Chemistry, in Valencia, Spain (2012.9).
  14. "Synthesis and Characterization of Bis-Heteroleptic Ru(II)-dmso Complex with 2,2’-Bipyridine and Unsymmetrical Ligand", Mari Toyama , Shun Shimizu, Tomokazu Ishida, and Noriharu Nagao, 4th Asian Conference on Coordination Chemistry, in Jeju, Korea (2013.11).
  15. " Syntheses and Structures of Dimetallic Ruthenium(II) Complexes bearing Bis-Didentate Bridging Ligand with a Central Pyrimidyl Group", Noriharu Nagao, Takashi Makise, and Mari Toyama, 4th Asian Conference on Coordination Chemistry, in Jeju, Korea (2013.11).
  16. "Synthesis, Structures, and Substitution Reactions of　Ruthenium(II) Complex bearing Liner Tridentate　Polypyridyl Ligand with Six-Membered Chelate Rings", Jung Won Choi, Jun-ya Okuda, Yu Muranaka, Mari Toyama, and Noriharu Nagao, 4th Asian Conference on Coordination Chemistry, in Jeju, Korea (2013.11).
  17. "Selective Synthesis and Structure of tris-heteroleptic Ruthenium(II) Complex Bearing unsymmetrical ligand", Mari Toyama , Shun Shimizu, Tomokazu Ishida, and Noriharu Nagao, 41st International Conference on Coordination Chemistry, in Singapore (2014.7).
  18. "Synthesis, Crystal Structure, and Photochemical Reaction of Tris-Heteroleptic Ru(II) Complex with Unsymmetrical Ligand", Mari TOYAMA; Shun SHIMIZU; Noriharu NAGAO, 5th Asian Conference on Coordination Chemistry (ACCC5) in Hong Kong (2015.7).
  19. "Photo-Triggered Chelate Ring-Opening Reaction of Heteroleptic Ru(II) Complexes with Acetylacetonato and Tri-2-pyridylamine", Tsuyoshi Fujii, Mari Toyama, and Noriharu Nagao, 5th Asian Conference on Coordination Chemistry (ACCC5) in Hong Kong (2015.7).
  20. " Thermal Substitution and Isomerization Reaction, and DFT Calculations of Bis-Heteroleptic Ru(II) Complexes with N-Methyl-di-(2-pyridyl)amine and 2,2'-Bipyridine", Naoto Kasai, Mari Toyama, and Noriharu Nagao, 5th Asian Conference on Coordination Chemistry (ACCC5) in Hong Kong (2015.7).
  21. "Syntheses, Structures, and Thermal Reaction of Bis-Heteroleptic Ru(II) Complexes with ddppd and mdpa", Yu Muranaka, Jun-ya Okuda, Mari Toyama, and Noriharu Nagao, 5th Asian Conference on Coordination Chemistry (ACCC5) in Hong Kong (2015.7).
  22. "Thermal and Photochemical Isomerization Reactions of Mononuclear Ru(II)-dmso Complex with an Unsymmetrical Bis-Bidentate Ligand", Taichi Takeuchi, Takashi Makise, Mari Toyama, and Noriharu Nagao, 5th Asian Conference on Coordination Chemistry (ACCC5) in Hong Kong (2015.7).
  23. "SYNTHESIS, CRYSTAL STRUCTURE, AND SOLUTION STRUCTURE OF CIS-BIS(DI-2-PYRIDYLAMINE)CHLORO(DIMETHYL SULFOXIDE-S)RUTHENIUM(II) COMPLEX", Mari Toyama, Daichi Mishima, Ryuji Suganoya, Noriharu Nagao, 6th Asian Conference on Coordination Chemistry (ACCC6), in Melbourne, Australia (2017.7).
  24. "Synthesis and Structure of Chloro(dimethyl sulfoxide)complex of Ruthenium(II) bearing Neutral N,O Ligand", N. Nagao, R. Tanaamia, M. Kishimoto, and M. Toyama, 43rd International Conference on Coordination Chemistry (ICCC) in 仙台 (2018.8).
  25. "Fluoride Sensor using (2-Picolinamide)Ru(II) Complex", M. Toyama, Y. Fujii, M. Endo, and N. Nagao, 43rd International Conference on Coordination Chemistry (ICCC) in 仙台 (2018.8).
  • External funds, patents, copyrights, etc.
  1. 外山真理（代表）,"貴金属イオンを含む溶液から貴金属を回収する光触媒の合成", 日本私立学校振興機構・共済事業団　女性研究者奨励金, 400,000円 (2018).
  2. 外山真理（代表），株式会社　青粒，”植物のネバネバ成分を用いたドラッグデリバリーへの応用に関する研究”，公益財団法人ひょうご科学技術協会　産学共同研究に関わる助成金, 150,000円（2018).
  3. 外山真理（代表），”目視で判定可能なフッ化物イオン検出能を持つ錯体の研究　～検出範囲の拡張・低コスト化を目指した改良～”，一般財団法人 ササクラ環境科学財団 平成３０年度（第２回）一般研究助成, 450,000円（2018).
  • Activities in academic societies

外山　真理　TOYAMA Mari

  • Department
    工学部　基礎理工学科　特任講師
  • Contribution in the local community


  • Committee members, officers, etc. in public institutions


  • Organization management such as academic societies


  • Disaster relief activities in Japan and overseas


  • Other

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