Osaka Electro-Communication University Faculty Information Database >青沼　秀児

Sustainable Chemistry Course Department of Engineering Science

青沼 秀児（あおぬま しゅうじ）AONUMA Shuji 画像の説明

  • Department
    工学部 環境科学科 准教授
    大学院 工学研究科 先端理工学専攻 准教授
  • Specialized field
  • Research theme
    高性能二次電池用有機電極材料の分子設計と合成
  • URL
  • Career
    • Educational background
      1982年 3月 京都府立北嵯峨高等学校 卒業
      1982年 4月 京都大学工学部石油化学科 入学
      1986年 3月 京都大学工学部石油化学科 卒業
      1986年 3月 京都大学大学院工学研究科博士前期課程(石油化学専攻) 入学
      1988年 3月 京都大学大学院工学研究科博士前期課程(石油化学専攻) 修了
      1988年 4月 京都大学大学院工学研究科博士後期課程(石油化学専攻) 進学
      1991年 3月 京都大学大学院工学研究科博士後期課程(石油化学専攻) 単位取得退学
      1991年 9月 博士(工学) (京都大学) 取得
    • Work history
      1991年 4月～2001年3月 東京大学物性研究所新物質開発部門 助手
      1998年 9月～2001年2月 Laboratoire de Chimie de Coordination du CNRS (フランス国立科学研究センター配位化学研究所, LCC-CNRS) 客員研究員 兼任
      2001年 4月～2007年3月 大阪電気通信大学工学部電子材料工学科 助教授
      2007年 4月～現在 大阪電気通信大学工学部応用化学科 准教授
      2011年 4月～現在 大阪電気通信大学工学部環境科学科 准教授
  • Degree, etc.
    博士(工学)
  • Awards, etc.
  • Academic societies
    日本化学会、有機合成化学協会、日本物理学会

青沼 秀児（あおぬま しゅうじ）AONUMA Shuji

  • Department
    工学部 環境科学科 准教授
    大学院 工学研究科 先端理工学専攻 准教授
  • Department / Faculty Management


  • Activities within the university, such as committees, centers, and research institutes


  • Collaboration activities with industry, government, and academia

  • External activities


  • Other

青沼 秀児（あおぬま しゅうじ）AONUMA Shuji

  • Department
    工学部 環境科学科 准教授
    大学院 工学研究科 先端理工学専攻 准教授
  • Undergraduate education (lectures)
    有機化学1
    有機化学2
    機器分析化学2

  • Graduate education (lecture)
    有機化学特論

  • Teaching thesis
    • 卒業論文等の指導: 82名
    • 修士論文等の指導: 8名
    • 博士論文等の指導: 0名

Teaching portfolio

  • Posture for class
  • Self-evaluation of educational activities
  • Training activities to improve classes
  • Active learning
  • Outline of main course subjects and achievement targets
  • Level of achievement against specific goals
  • Responding to requests from students

青沼 秀児（あおぬま しゅうじ）AONUMA Shuji

  • Department
    工学部 環境科学科 准教授
    大学院 工学研究科 先端理工学専攻 准教授
  • Books etc：
  1. 青沼, 「第4章[2]キノイド化合物を用いた有機二次電池」, リチウムに依存しない革新型二次電池, エヌ・ティー・エス(2013) (分担)
  2. 青沼, 「第8章第7節 高性能二次電池用有機正極材料としてのキノイド化合物の分子設計と合成」, 次世代蓄電池の【最新】材料技術と性能評価, 技術情報協会 (2013). (分担)

  • Academic papers, works, etc.
    • Full Paper
  1. K. Okamoto, T. Kitagawa, K. Takeuchi, K. Komatsu, T. Kinoshita, S. Aonuma, M. Nagai, and A. Miyabo, “Isolation and Properties of Hydrocarbon Salts”, J. Org. Chem., Vol. 55, No. 3, pp. 996-1002, 1990.
  2. K. Komatsu, S. Aonuma, Y. Jinbu, R. Tsuji, C. Hirosawa, and K. Takeuchi, “Generation and Oligomerization of Bicyclo[2.2.2]octyne and Properties of Tris(bicyclo[2.2.2]octeno)benzene Obtained from the Linear Trimer”, J. Org. Chem., Vol. 56, No. 1, pp. 195-203, 1991.
  3. K. Komatsu, H. Akamatsu, S. Aonuma, Y. Jinbu, N. Maekawa, and K. Takeuchi, "Formation, Properties, and Reactions of the 1,2:3,4:5,6-Tris(bicyclo[2.2.2]octeno)tropylium Ion", Tetrahedron, Vol. 47, No. 34, pp. 6951-6966, 1991.
  4. S. Aonuma, H. Sawa, Y. Okano, R. Kato, and H. Kobayashi, “Synthesis of DMe-DCNQI-¬d7 and Deuterium-Induced Metal-Insulator Transition of (DMe-DCNQI-¬d7)2Cu”, Synth. Met., Vol. 58, No. 1, pp. 29-38, 1993.
  5. R. Kato, S. Aonuma, Y. Okano, H. Sawa, M. Tamura, K. Oshima, A. Kobayashi, K. Bun, and H. Kobayashi, “Metallic and Superconducting Salts Based on an Unsymmetrical -Donor Dimethyl(ethylenedithio)tetraselenafulvalene (DMET-TSeF)”, Synth. Met., Vol. 61, No. 3, pp. 199-206, 1993.
  6. S. Uji, T. Terashima, H. Aoki, J. S. Brooks, R. Kato, H. Sawa, S. Aonuma, M. Tamura, and M. Kinoshita, “Coexistence of One-and Three-Dimensional Fermi Surface and Heavy Cyclotron Mass in the Molecular Conductor (DMe-DCNQI”2Cu", Phys. Rev. B, Vol. 50, No. 21, pp. 15597-15601, 1994.
  7. S. Aonuma, H. Sawa, and R. Kato, “Chemical Pressure Effect by Selective Deuteration in Molecular-Based Conductor, (DMe-DCNQI)2Cu”, J. Chem. Soc, Perkin Trans. 2, No. 7, pp. 1541-1549, 1995.
  8. K. Hiraki, Y Kobayashi, T. Nakamura, T. Takahashi, S. Aonuma, H. Sawa, R. Kato, and H. Kobayashi, “Magnetic Structure in the Antiferromagnetic State of the Organic Conductor (DMe-DCNQI[3,3;l]d7)2Cu: 1H-NMR Analysis”, J. Phys. Soc. Jpn., Vol. 64, No. 6, pp. 2203-2211, 1995.
  9. H. Tajima, S. Aonuma, H. Sawa, and R. Kato, “Infrared Reflectance Spectra of (Me2DCNQI-d7)2Cu”, J. Phys. Soc. Jpn., Vol. 64, No. 7, pp. 2502-2509, 1995.
  10. S. Hill, P. S. Sandhu, M. E. J. Boonman, J. A. A. J. Perenboom, A. Wittlin, S. Uji, J. S. Brooks, R. Kato, H. Sawa, and S. Aonuma, “Magnetoelectrodynamics of a Three-dimensional Organic Conductor: Observation of Cyclotron Resonance in d2[l,l;0]-(DMe-DCNQI)2Cu”, Phys. Rev. B, Vol. 54, No. 19, pp. 13536-13541, 1996.
  11. R. Kato, Y.-L. Liu, Y Hosokoshi, S. Aonuma, and H. Sawa, “Se-Substitution and Cation Size Effect on the High-Pressure Molecular Superconductor, -Me4N[Pd(dmit)2]2 —A Unique Two-band System—”, Mol. Cryst. Liq. Cryst., Vol. 296, pp. 217-244, 1997.
  12. A. Sekiyama, A. Fujimori, S. Aonuma, and R. Kato, “Observation of Anisotropy in the Electronic States of N,N'-Dicyanoquinonediimine-Cu Salt by X-Ray-absorption Spectrosopy”, Phys. Rev. B, Vol. 56, No. 15, pp. 9937-9941, 1997.
  13. T. Yamamoto, H. Tajima, J. Yamaura, S. Aonuma, and R. Kato, “Reflectance Spectra and Electrical Resistivity of (Me2-DCNQI)2Li1-xCux”, J. Phys. Soc. Jpn., Vol. 68, No. 4, pp. 1384-1391, 1999.
  14. Y Nishio, M. Tamura, K. Kajita, S. Aonuma, H. Sawa, R. Kato, and H. Kobayashi, “Thermodynamical Study of (DMe-DCNQI)2Cu System —Mechanism of Reentrant Metal-Insulator Transitioiy—”, J. Phys. Soc. Jpn., Vol. 69, No. 5, pp. 1414-1422, 2000.
  15. S. Aonuma, H. Casellas, C. Faulmann, B. Garreau de Bonneval, I. Malfant, P. Cassoux, P. G. Lacroix, Y. Hosokoshi, and K. Inoue, “Structure and Properties of Novel M(dmit)2 Salts with the Me3N+-TEMPO Cation Radical (Me3N+-TEMPO = N,N,N-trimethyl (1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)ammonium)”, J. Mater. Chem., Vol. 11, No. 2, pp. 337-345, 2001.
  16. T. Nakamura, T. Takahashi, S. Aonuma, and R. Kato, “EPR Investigation of the Electronic States in β'-type [Pd(dmit)2]2 Compounds (where dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate),” J. Mater. Chem., Vol. 11, No. 9, pp. 2159-2162, 2001.
  17. Y. Nishio, Y. Mori, S. Sasaki, K. Kajita, S. Aonuma, H. Sawa, M. Tamura, R. Kato, “Schottky Specific Heat Due to the Tunneling Rotation of Methyl Groups in Deuterated (DMe-DCNQI)2Cu”, J. Phys. Soc. Jpn., Vol. 71, No. 7, pp. 1701-1704, 2002.
  18. S. Bhattacharya, N. Ujihashi, S. Aonuma, T. Kimura, and N. Komatsu, “Spectral and Theoretical Studies on Effective and Selective Non-covalent Interaction between Tetrahexylporphyrins and Fullerenes”, Spectrochimica Acta A, Vol. 68, pp. 495-503, 2007.
    • Letter
  1. K. Komatsu, T. Takai, S. Aonuma, and K. Takeuchi, “A 13C NMR Study on the Tris(phenylethynyl)methyl and ,-Bis(phenylethynyl)benzyl Cations: the Tris-and Bis-Ethynologues of the Triphenylmethyl Cation”, Tetrahedron Lett., Vol. 29, No. 40, pp. 5157-5160, 1988.
  2. K. Komatsu, S. Aonuma, K. Takeuchi, and K. Okamoto, “The Hydrocarbon Cation-Anion System in Which Ionic, Radical, and Covalent Species Coexist in Equilibria”, J. Org. Chem., Vol. 54, No. 9, pp. 2038-2039, 1989.
  3. S. Aonuma, K. Komatsu, and K. Takeuchi, “Energy Barriers for the Ring Inversion of 1,2:3,4:5,6-Tris(bicyclo[2.2.2]octeno)- and 1,2,3,4,5,6-Hexamethylcycloheptatrienes”, Chem. Lett., No. 12, pp. 2107-2110, 1989.
  4. S. Aonuma, K. Komatsu, N. Maekawa, and K. Takeuchi, “Enhanced Polarization of Heptafulvene and Tropone by Annelation with Three Bicyclo[2.2.2]octene Frameworks”, Chem. Lett., No. 5, pp. 767-770, 1991.
  5. K. Komatsu, T. Nishinaga, S. Aonuma, C. Hirosawa, K. Takeuchi, H. J. Lindner, and J. Richter, “Synthesis, Structure, and Reduction of the Cyclooctatetraene Tetra-Annelated with Bicyclo[2.2.2]octene Frameworks”, Tetrahedron Lett., Vol. 32, No. 46, pp. 6767-¬6770, 1991.
  6. S. Aonuma, Y Okano, H. Sawa, R. Kato, and H. Kobayashi, “Stable Molecular Metals Based on a Novel Unsymmetrical Diselenadithiafulvalene”, J. Chem. Soc, Chem. Commun., No. 17, pp. 1193-1195, 1992.
  7. S. Aonuma, H. Sawa, R. Kato, and H. Kobayashi, “Giant Metal-Insulator-Metal Transition Induced by Selective Deuteration of the Molecular Conductor, (DMe-DCNQI)2Cu (DMe-DCNQI = 2,5-dimethyl-N,N'-dicyanoquinonediimine)”, Chem. Lett., No. 3, pp. 513-516, 1993.
  8. R. Kato, H. Sawa, S. Aonuma, M. Tamura, M. Kinoshita, and H. Kobayashi, “Preparation and Physical Properties of an Alloyed (DMe-DCNQI)2Cu with Fully Deuterated DMe-DCNQI (DMe-DCNQI = 2,5-dimethyl-N,N'-dicyanoquinonediimine)”, Solid State Commun., Vol. 85, No. 10, pp. 831-835, 1993.
  9. H. Sawa, M. Tamura, S. Aonuma, R. Kato, M. Kinoshita, and H. Kobayashi, “Novel Electronic States of Partially Deuterated (DMe-DCNQI)2Cu”, J. Phys. Soc. Jpn., Vol. 62, No. 7, pp. 2224-2228, 1993.
  10. M. Tamura, H. Sawa, S. Aonuma, R. Kato, M. Kinoshita, and H. Kobayashi, “Weak Ferromagnetism and Magnetic Anistropy in Cu Salt of Fully Deuterated DMe-DCNQI, (DMe-DCNQI-d8)2Cu”, J. Phys. Soc. Jpn., Vol. 62, No. 5, pp. 1470-1473, 1993.
  11. H. Kobayashi, H. Sawa, S. Aonuma, and R. Kato, “Evidence for Reentrant Structural-Phase Transition in DCNQI-Cu System”, J. Am. Chem. Soc., Vol. 115, No. 17, pp. 7870-7871, 1993.
  12. Y Okano, H. Sawa, S. Aonuma, and R. Kato, “Synthesis, Conductivity, and Structure of a Novel Organic Conductor (TMET-STF)2ClO4. Coexistence of One-and Two-dimensional Donor Columns”, Chem. Lett., No. 11, pp. 1851-1854, 1993.
  13. M. Tamura, H. Sawa, Y Kashimura, S. Aonuma, R. Kato, and M. Kinoshita, “Weak Ferromagnetism in (DBr-DCNQI)2Cu (DBr-DCNQI = 2,5-dibromo-N,N'¬dicyanoquinonediimine)”, J. Phys. Soc. Jpn., Vol. 63, No. 2, pp. 425-428, 1994.
  14. M. Tamura, H. Sawa, S. Aonuma, R. Kato, and M. Kinoshita, “Magnetic Study of Metal-Insulator-Metal Transitions in (DMe-DCNQI-,'-d2)2Cu”, J. Phys. Soc. Jpn., Vol. 63, No. 2, pp. 429-432, 1994.
  15. H. Sawa, M. Tamura, S. Aonuma, M. Kinoshita, and R. Kato, “Charge Transfer Controlled Phase Transition in a Molecular Conductor, (DMe-DCNQI)2Cu —Doping Effect—”, J. Phys. Soc. Jpn., Vol. 63, No. 12, pp. 4302-4305, 1994.
  16. R. Kato, S. Aonuma, H. Sawa, K. Hiraki, and T. Takahashi, “Unexpected Isotope Effect in 13C-substituted (-CN) Molecular Conductor (DMe-DCNQI)2Cu (DMe-DCNQI = 2,5-dimethyl-N,N'-dicyano-p-quinonediimine)”, Synth. Met., Vol. 68, No. 2, pp. 195-198, 1995.
  17. S. Uji, T. Terashima, H. Aoki, R. Kato, H. Sawa, S. Aonuma, M. Tamura, and M. Kinoshita, “Fermi Surface and Absence of Additional Mass Enhancement near the Insulating Phase in (DMe-DCNQI)2Cu”, Solid State Commun., Vol. 93, No. 3, pp. 203-207, 1995.
  18. M. Tamura, Y Kashimura, H. Sawa, S. Aonuma, R. Kato, and M. Kinoshita, “Enhanced Magnetic Susceptibility of (DI-DCNQI)2Cu”, Solid State Commun., Vol. 93, No. 7, pp. 585-588, 1995.
  19. Y Kashimura, H. Sawa, S. Aonuma, R. Kato, H. Takahashi, and N. Mori, “Anomalous Pressure-Temperature Phase Diagram of the Molecular Conductor, (DI-DCNQI)2Cu (DI-DCNQI = 2,5-Diiodo-N,N'-dicyanoquinonediimine)”, Solid State Commun., Vol. 93, No. 8, pp. 675-679, 1995.
  20. R. Kato, Y L. Liu, H. Sawa, S. Aonuma, A. Ichikawa, H. Takahashi, and N. Mori, “Structures and Properties of New Molecular Conductors Based on Pd(dmise)2 (dmise = 2-Selenoxo-l,3-dithiole-4,5-dithiolate)”, Solid State Commun., Vol. 94, No. 12, pp. 973-977, 1995.
  21. A. Sekiyama, A. Fujimori, S. Aonuma, H. Sawa, and R. Kato, “Fermi-liquid versus Luttinger-liquid Behavior and Metal-Insulator Transition in N,N'-dicyanoquinonediimine-Cu Salt Studied by Photoemission”, Phys. Rev. B, Vol. 51, No. 19, pp. 13899-13902, 1995
  22. R. Kato, Y L. Liu, S. Aonuma, and H. Sawa, “Cation Size Effect in Molecular Conductors Related to the High-Pressure Superconductors -Me4N[Pd(dmit)2]2 (dmit = 2-thioxo-l,3¬dithiole-4,5-dithiolate)”, Solid State Commun., Vol. 98, No. 11, pp. 1021-1025, 1996.
  23. A. Sekiyama, A. Fujimori, S. Aonuma, H. Sawa, and R. Kato, “High-resolution Photoemission and X-Ray Absorption Study of Quasi-one-dimensional DCNQI-Cu Salt”, J. Electron Spectrosc. Relat. Phenom., Vol. 78, pp. 472-476, 1996.
  24. R. Kato, Y Kashimura, S. Aonuma, N. Hanasaki, and H. Tajima, “A New Molecular Superconductor (’-Et2Me2P)[Pd(dmit)2]2 (dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate)”, Solid State Commun., Vol. 105, No. 9, pp. 561-565, 1998.
  25. A. Sekiyama, A. Fujimori, S. Aonuma, R. Kato, T. Iwasaki, S. Suga, H. Ishii, T. Matsushita, and T. Miyahara, “X-Ray Photoemission Study of an Organic Quasi-1D DCNQI-Cu Salt”, J. Electron Spectrosc. Relat. Phenom., Vol. 88, pp. 939-943, 1998.
  26. S. Bhattacharya, T. Shimawaki, X. Peng, A. Ashokkumar, S. Aonuma, T. Kimura, and N. Komatsu, “Spectroscopic and Theoritical Investigations on Effective and Selective Complexation between Porphyrins and Fullerenes”, Chem. Phys. Lett., Vol. 430, pp. 435-442, 2006.
  27. N. Komatsu, T. Shimawaki, S. Aonuma and T. Kimura, “Ultrasonic Isolation of Toroidal Aggregates of Single-Walled Carbon Nanotubes”, Carbon, Vol. 44, pp. 2093-2095, 2006.
  28. X. Peng, N. Komatsu, S. Bhattacharya, T. Shimawaki, S. Aonuma, T. Kimura, A. Osuka, “Optically Active Single-Walled Carbon Nanotubes”, Nature Nanotechnology Vol. 2, pp. 361-365, 2007.
  29. E. Fujiwara, S. Aonuma, H. Fujiwara, T. Sugimoto, Y. Misaki, “New -Electron Donors with a 2,2,5,5-Tetramethylpyrrolin-1-yloxyl Radical Designed for Magnetic Molecular Conductors”, Chem. Lett,. Vol. 37, No. 1, pp. 84-85, 2008.
  30. Y. Morita, T. Takimoto, H. Yamanaka, K. Kumekawa, S. Morino, S. Aonuma, T. Kimura, N. Komatsu, “A Facile and Scalable Process for Size-Controllable Separation of Nanodiamond as Small as 4 nm”, Small, Vol. 4, pp. 2154-2157, 2008.
  31. M. Yasuda, E. Fujiwara, S. Aonuma, H. Fujiwara, T. Sugimoto, T. Nakayashiki, K. Tanaka, K. Takahashi, H. Kobayashi and Y. Misaki, “Structures and Electrical Properties of (BTM-TS-TTP)4PF6”, Bull. Chem. Soc. Jpn., Vol. 84, No. 1, pp. 79-81, 2011.
    • Proceedings (Peer-reviewed)
  1. R. Kato, H. Sawa, S. Aonuma, Y Okano, S. Kagoshima, A. Kobayashi, and H. Kobayashi, “Metallic Behavior Induced by Li-Doping in DCNQI-Cu System”, Synth. Met., Vol. 56, No. 1, pp. 1864-1869, 1993, the International Conference on Science and Technology of Synthetic Metals (ICSM '92), Goteborg, Sweden (Aug. 12-18, 1992).
  2. R. Kato, S. Aonuma, Y Okano, and H. Sawa, “Multivarious Faces of Organic Metals Based on Se-substituted BEDT-TTF Family”, Synth. Met., Vol. 56, No. 1, pp. 2084-2089, 1993, the International Conference on Science and Technology of Synthetic Metals (ICSM f92), Goteborg, Sweden (Aug. 12-18, 1992).
  3. T. Nakamura, K. Hiraki, Y Kobayashi, T. Takahashi, S. Aonuma, H. Sawa, R. Kato, and H. Kobayashi, “Magnetic Structure in Antiferromagnetic States of a Molecular Conductor, (DMe-DCNQI-d7)2Cu”, Physica B, Vol. 194-196, pp. 231-232, 1994, the 20th International Conference on Low Temperature Physics, Eugene, Oregon, USA (Aug 4-11, 1993).
  4. H. Sawa, Y Okano, S. Aonuma, and R. Kato, “Crystal and Electronic Structure of (BPDT-TSeF)-Ni(dmit)2 System. BPDT-TSeF = Bis(propylenedithio)tetraselenafulvalene”, Synth. Met., Vol. 70, No. 1-3, pp. 1055-1056, 1995, the International Conference on Science and Technology of Synthetic Metals (ICSM '94), Seoul, Korea (Jul. 24-29, 1994).
  5. K. Hiraki, K. Takagawa, T Nakamura, T. Takahashi, S. Aonuma, H. Sawa, and R. Kato, “Re-entrant Phenomena of the Organic Conductor, DCNQI-Cu Salts”, Synth. Met., Vol. 70, No. 1-3, pp. 1069-1070, 1995, the International Conference on Science and Technology of Synthetic Metals (ICSM '94), Seoul, Korea (Jul. 24-29, 1994).
  6. R. Kato, S. Aonuma, and H. Sawa, “Selectively Deuterated Molecular Conductor (DMe-DCNQI)2Cu —Phase Diagram and Dimensionality—“, Synth. Met., Vol. 70, No. 1-3, pp. 1071-1074, 1995, the International Conference on Science and Technology of Synthetic Metals (ICSM '94), Seoul, Korea (Jul. 24-29, 1994).
  7. S. Uji, T. Terashima, H. Aoki, J. S. Brooks, R. Kato, H. Sawa, S. Aonuma, M. Tamura, and M. Kinoshita, “Fermi Surface and Cyclotron Mass in (DMe-DCNQI)2Cu”, Synth. Met., Vol. 70, No. 1-3, pp. 1075-1076, 1995, the International Conference on Science and Technology of Synthetic Metals (ICSM '94), Seoul, Korea (Jul. 24-29, 1994).
  8. R. Kato, Y Kashimura, H. Sawa, S. Aonuma, M. Tamura, M. Kinoshita, H. Takahashi, and N. Mori, “Crystal Structure and Physical Properties of Molecular Metal (DI¬DCNQI)2Cu (DI-DCNQI = 2,5-diiodo-N,N'-dicyano-p-quinonediimine)”, Synth. Met., Vol. 70, No. 1-3, pp. 1077-1078, 1995, the International Conference on Science and Technology of Synthetic Metals (ICSM'94),Seoul, Korea (Jul.24-29, 1994).
  9. M. Tamura, H. Sawa, Y Kashimura, S. Aonuma, R. Kato, and M. Kinoshita, “Magnetic Properties of DCNQI-Cu Systems”, Synth. Met., Vol. 70, No. 1-3, pp. 1081-1082, 1995, the International Conference on Science and Technology of Synthetic Metals (ICSM '94), Seoul, Korea (Jul. 24-29, 1994).
  10. H. Sawa, M. Tamura, S. Aonuma, M. Kinoshita, and R. Kato, “Charge Transfer and Reentrant Phenomenon in Deuterated (DMe-DCNQI)2Cu”, Synth. Met., Vol. 70, No. 1-3, pp. 1085-1086, 1995, the International Conference on Science and Technology of Synthetic Metals (ICSM '94), Seoul, Korea (Jul. 24-29, 1994).
  11. S. Aonuma, H. Sawa, and R. Kato, “Selectively Deuterated Molecular Conductor (DMe-DCNQI)2Cu — Preparation and Chemical Pressure Effect —“, Synth. Met., Vol. 70, No. 1-3, pp. 1089-1090, 1995, the International Conference on Science and Technology of Synthetic Metals (ICSM '94), Seoul, Korea (Jul. 24-29, 1994).
  12. K. Hiraki, Y Kobayashi, T. Nakamura, T. Takahashi, S. Aonuma, H. Sawa, R. Kato, and H. Kobayashi, “Magnetic Structure in the Antiferromagnetic State of DCNQI-Cu Salts”, Synth. Met., Vol. 70, No. 1-3, pp. 1091-1092, 1995, the International Conference on Science and Technology of Synthetic Metals (ICSM '94), Seoul, Korea (Jul. 24-29, 1994).
  13. Y Okano, H. Sawa, S. Aonuma, and R. Kato, “TMET-STF Salts. A Variety of Crystal and Electronic Structures. (TMET-STF = Trimethylene(ethylenedithio)¬diselenadithiafulvalene)”, Synth. Met., Vol. 70, No. 1-3, pp. 1161-1162, 1995, the International Conference on Science and Technology of Synthetic Metals (ICSM '94), Seoul, Korea (Jul. 24-29, 1994).
  14. Y Nishio, T. Tega, K. Kajita, H. Kobayashi, S. Aonuma, H. Sawa, and R. Kato, “Giant Peak in the Specific Heat of Selectively Deuterated (DMe-DCNQI)2Cu”, Synth. Met., Vol. 70, No. 1-3, pp. 1947-1948, 1995, the International Conference on Science and Technology of Synthetic Metals (ICSM '94), Seoul, Korea (Jul. 24-29, 1994).
  15. M. Tamura, H. Sawa, Y Kashimura, S. Aonuma, R. Kato, and M. Kinoshita, “(DCNQI)2Cu: Variety of Magnetism Arising form p-d Interactions”, Mol. Cryst. Liq. Cryst., Vol. 271, pp. 13-18, 1995, the Fourth International Conference on Molecular-Based Magnets, Salt Lake City, Utah, USA (Oct. 16-21, 1994).
  16. R. Kato, S. Aonuma, and H. Sawa, “Chemical Control of the Electronic States in the p-d System”, Mol. Cryst. Liq. Cryst., Vol. 284, pp. 183-194, 1996, the Symposium on Advances in the Chemistry and Properties of Novel Low-Dimensional and Conducting or Superconducting Solids, Honolulu, Hawaii, USA (Dec. 17-22, 1995).
  17. H. Sawa, Y L. Liu, S. Aonuma, and R. Kato, “Novel Pressure-Temperature Phase Diagram of Molecular Conductors Related to the High-Pressure Superconductor, (-Me4N[Pd(dmit2]2"”, Mol. Cryst. Liq. Cryst., Vol. 285, pp. 131-136, 1996, Nagoya Conference “Perspective in Organic-Inorganic Hybrid Solids” — Molecular Design and Functionality—, Nagoya, Japan (Mar. 14-16, 1996).
  18. R. Kato, Y Kashimura, S. Aonuma, H. Sawa, H. Takahashi, and N. Mori, “p-d Interaction in the (R1,R2-DCNQI)2Cu System”, Mol. Cryst. Liq. Cryst., Vol. 285, pp. 143-150, 1996, Nagoya Conference “Perspective in Organic-Inorganic Hybrid Solids” — Molecular Design and Functionality—, Nagoya, Japan (Mar. 14-16, 1996).
  19. M. Tamura, N. Someya, Y Nishio, K. Kajita, Y Kashimura, S. Aonuma, H. Sawa, and R. Kato, “Correlation between the Thermal and Magnetic Properties of (DCNQI)2Cu”, Mol. Cryst. Liq. Cryst., Vol. 285, pp. 151-156, 1996, Nagoya Conference “Perspective in Organic-Inorganic Hybrid Solids” — Molecular Design and Functionality —, Nagoya, Japan (Mar. 14-16, 1996).
  20. S. Aonuma, H. Sawa, and R. Kato, “Anomalous 13C/15N Isotope Effect in the -d System (DMe-DCNQI)2Cu Studied by Selective Isotope Substitution”, Mol. Cryst. Liq. Cryst., Vol. 285, pp. 163-168, 1996, Nagoya Conference “Perspective in Organic-Inorganic Hybrid Solids” — Molecular Design and Functionality —, Nagoya, Japan (Mar. 14-16, 1996).
  21. T. Sekine, K. Tsutsumi, Y Tanokura, S. Aonuma, H. Sawa, and R. Kato, “Raman Scattering in Organic Conductors (DMe-DCNQI)2Cu”, Physica B, Vol. 219&220, pp. 532¬534, 1996, the Combined Conference of the 4th International Conference on Phonon Physics and the 8th International Conference on Phonon Scattering in Condensed Matter (PHONONS 95), Sapporo, Japan (Jul. 23-28, 1995).
  22. Y Nishio, T. Tega, M. Tamura, K. Kajita, S. Aonuma, H. Sawa, R. Kato, and H. Kobayashi, “Thermal Study of Antiferromagnetic Ordering in Deuterated (DMe-DCNQI)2Cu”, Synth. Met., Vol. 85, No. 1-3, pp. 1739-1740, 1997, the International Conference on Science and Technology of Synthetic Metals (ICSM '96), Snowbird, Utah, USA (Jul. 28-Aug. 2, 1996).
  23. S. Aonuma, H. Sawa, and R. Kato, “Preparation, Structure and Conductivity of Et2Me2Z (Z = P, As, Sb) Salts of M(dmit)2 and M(dmise)2 (M = Ni, Pd)”, Synth. Met., Vol. 86, No. 1-3, pp. 1881-1882, 1997, the International Conference on Science and Technology of Synthetic Metals (ICSM '96), Snowbird, Utah, USA (Jul. 28-Aug. 2, 1996).
  24. K. Takagawa, N. Maruyama, K. Hiraki, T. Nakamura, T. Takahashi, Y Kashimura, S. Aonuma, H. Sawa, and R. Kato, “13C-NMR Studies of the Metallic State of (DMe-DCNQI)2Cu”, Synth. Met., Vol. 86, No. 1-3, pp. 1915-1916, 1997, the International Conference on Science and Technology of Synthetic Metals (ICSM '96), Snowbird, Utah, USA (Jul. 28-Aug. 2, 1996).
  25. K. Oshima, H. Okuno, H. Fujimura, Y Nogami, S. Aonuma, and R. Kato, “Characteristic SDW and FISDW Behavior in (DMET-TSeF)2X System”, Synth. Met., Vol. 86, No. 1-3, pp. 1965-1966, 1997, the International Conference on Science and Technology of Synthetic Metals (ICSM '96), Snowbird, Utah, USA (Jul. 28-Aug. 2, 1996).
  26. T. Sekine, T. Kamioka, R. Kawano, K. Tsutsumi, Y Tanokura, S. Aonuma, H. Sawa, and R. Kato, “Observation of the Order of Cu Ions in the Mixed-valence State of (DMe-DCNQI)2Cu by Raman Scattering”, Synth. Met., Vol. 86, No. 1-3, pp. 2071-2072, 1997, the International Conference on Science and Technology of Synthetic Metals (ICSM '96), Snowbird, Utah, USA (Jul. 28-Aug. 2, 1996).
  27. N. Someya, Y Nishio, M. Tamura, K. Kajita, S. Aonuma, H. Sawa, R. Kato, and H. Kobayashi, “Thermal Study of Reentrant Metal-Insulator Transition in deuterated (DMe-DCNQI)2Cu”, Synth. Met., Vol. 86, No. 1-3, pp. 2077-2078, 1997, the International Conference on Science and Technology of Synthetic Metals (ICSM '96), Snowbird, Utah, USA (Jul. 28-Aug. 2, 1996).
  28. R. Kato, Y.-L. Liu, S. Aonuma, and H. Sawa, “Molecular Conductors Based on Pd(dmit)2 and Related Metal Dithiolene Complexes — A Unique Two-band System —”, Synth. Met., Vol. 86, No. 1-3, pp. 2087-2088, 1997, the International Conference on Science and Technology of Synthetic Metals (ICSM '96), Snowbird, Utah, USA (Jul. 28-Aug. 2, 1996).
  29. H. Sawa, S. Aonuma, Y Kashimura, and R. Kato, “Novel Electronic State in the (DCNQI)2Cu System”, Synth. Met., Vol. 86, No. 1-3, pp. 2091-2092, 1997, the International Conference on Science and Technology of Synthetic Metals (ICSM '96), Snowbird, Utah, USA (Jul. 28-Aug. 2, 1996).
  30. N. Maruyama, T. Nakamura, T. Takahashi, S. Aonuma, H. Sawa, and R. Kato, “1H-NMR Studies of (DMe-DCNQI-d7)2Cu1-xLix”, Synth. Met., Vol. 86, No. 1-3, pp. 2093-2094, 1997, the International Conference on Science and Technology of Synthetic Metals (ICSM '96), Snowbird, Utah, USA (Jul. 28-Aug. 2, 1996).
  31. H. Tajima, S. Aonuma, H. Sawa, and R. Kato, “Infrared Reflectance Spectra of DCNQI Salts”, Synth. Met., Vol. 86, No. 1-3, pp. 2101-2102, 1997, the International Conference on Science and Technology of Synthetic Metals (ICSM '96), Snowbird, Utah, USA (Jul. 28-Aug. 2, 1996).
  32. S. Hill, P. S. Sandhu, M. Boonman, S. Uji, J. A. A. J. Perenboom, A. Wittlin, J. S. Brooks, R. Kato, H. Sawa, and S. Aonuma, “Cyclotron Resonance Studies of the Molecular Conductor d2[l,l;0]-(DMe-DCNQI)2Cu”, Synth. Met., Vol. 86, No. 1-3, pp. 2113-2114, 1997, the International Conference on Science and Technology of Synthetic Metals (ICSM '96), Snowbird, Utah, USA (Jul. 28-Aug. 2, 1996).
  33. F. L. Pratt, P. A. Pattenden, S. J. Blundell, T. Jestadt, K. H. Chow, W. Hayes, R. Kato, M. Tamura, H. Sawa, and S. Aonuma, “Zero Field SR and QLCR in the Molecular Metal System (DMe-DCNQI)2Cu”, Hyperfine Interactions, Vol. 104, No. 1-4, pp. 357-362, 1997, 7th International Conference on Muon Spin Rotation/Relaxation/Resonance, Nikko, Japan (Apr. 15-19, 1996).
  34. S. Aonuma and R. Kato, “Anomalous Role of Carbon and Nitrogen Isotopes in (DMe-DCNQI)2Cu System”, Synth. Met., Vol. 102, No. 1-3, pp. 1749-1750, 1999, the International Conference on Science and Technology of Synthetic Metals (ICSM '98), Montpellier, France (Jul. 12-18, 1998).
  35. K. Oshima, T. Sasaki, M. Motokawa, S. Aonuma, and R. Kato, “High Field Hall Effect in (DMET-TSeF)2AuCl2”, Synth. Met., Vol. 103, No. 1-3, pp. 1917-1918, 1999, the International Conference on Science and Technology of Synthetic Metals (ICSM '98), Montpellier, France (Jul. 12-18, 1998).
  36. S. Rouziere, R. Kato, S. Aonuma, and H. Sawa, “Low Temperature X-ray Studies of '-Pd(dmit)2 Salts”, Synth. Met., Vol. 103, No. 1-3, pp. 1942-1943, 1999, the International Conference on Science and Technology of Synthetic Metals (ICSM '98), Montpellier, France (Jul. 12-18, 1998).
  37. R. Kato, K. Yamamoto, Y Kashimura, Y Okano, and S. Aonuma, “Two-band System: A Candidate for New Molecular Materials”, Synth. Met., Vol. 103, No. 1-3, pp. 2020-2023, 1999, the International Conference on Science and Technology of Synthetic Metals (ICSM '98), Montpellier, France (Jul. 12-18, 1998).
  38. T. Nakamura, H. Yamane, T. Takahashi, S. Aonuma, and R. Kato, “ESR and NMR Investigation of '-R4Z[Pd(dmit)2]2”, Synth. Met., Vol. 103, No. 1-3, pp. 2142-2142, 1999, the International Conference on Science and Technology of Synthetic Metals (ICSM '98), Montpellier, France (Jul. 12-18, 1998).
  39. H. Tajima, T. Yamamoto, J. Yamaura, S. Aonuma, and R. Kato, “The Study of 4kF CDW in a One-dimensional System, (DMe-DCNQI)2Li1-xCux”, Synth. Met., Vol. 103, No. 1-3, pp. 2193-2194, 1999, the International Conference on Science and Technology of Synthetic Metals (ICSM '98), Montpellier, France (Jul. 12-18, 1998).
  40. M. Yamane, T. Nakamura, T. Takahashi, S. Aonuma, R. Kato, and H. Sawa, “Impurity Effect on the Spin-Peierls State of (DMe-DCNQI) 2Cu1-xLix”, Synth. Met., Vol. 103, No. 1-3, pp. 2196, 1999, the International Conference on Science and Technology of Synthetic Metals (ICSM '98), Montpellier, France (Jul. 12-18, 1998).
  41. T. Yamamoto, N. Hanasaki, J. Yamaura, S. Aonuma, H. Tajima, K. Yakushi, M. Uruichi, and R. Kato, “Phase Diagrams of (DMe-DCNQI)2Li1-xCux System”, Synth. Met., Vol. 120, No. 1-3, pp. 873-874, 2001, the International Conference on Science and technology of Synthetic Metals (ICSM2000), Gastein, Austria (Jul. 15-21,2000).
  42. S. Aonuma, H. Casellas, C. Faulmann, B. Garreau de Bonneval, I. Malfant, P. G. Lacroix, P. Cassoux, Y. Hosokoshi, and K. Inoue, “Structure and Properties of M(dmit)2 Salts of Cations with a Magnetic Nitroxide Radical”, Synth. Met., Vol. 120, No. 1-3, pp. 993-994, 2001, the International Conference on Science and technology of Synthetic Metals (ICSM2000), Gastein, Austria (Jul. 15-21,2000).
  43. Y Nishio, S. Sasaki, M. Tamura, K. Kajita, S. Aonuma, H. Sawa, and R. Kato, “Anomalous Specific Heat of (DMe-DCNQI d2[l;l;0]1-x d4[2;2;0]x)2Cu-System”, Synth. Met., Vol. 120, No. 1-3, pp. 1047-1048, 2001. the International Conference on Science and Technology of Synthetic Metals (ICSM 2000), Gastein, Austria (Jul. 15-21, 2000).
  44. P. Cassoux, C. Faulmann, B. Garreau de Bonneval, I. Malfant, S. Aonuma, and M. E. Sanchez, “New Salts Derived from BETS and M(dmit)2 Molecules with Magnetic or Long-lived Excited State Counter-ions”, Synth. Met., Vol. 120, No. 1-3, pp. 1085-1086, 2001, the International Conference on Science and technology of Synthetic Metals (ICSM2000), Gastein, Austria (Jul. 15-21,2000).
  45. T. Nakamura, T. Takahashi, S. Aonuma, R. Kato, “g-Tensor Analyses of '-Type Pd(dmit)2 Metal Complexes”, Mol. Cryst. Liq. Cryst., Vol. 379, pp. 53-58, 2002. International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2000), Honolulu, Hawaii, USA (Dec. 11-14, 2000).
  46. S. Aonuma, H. Casellas, B. Garreau de Bonneval, C. Faulmann, I. Malfant, P. Cassoux, Y. Hosokoshi, and K. Inoue, “Structure and Properties of M(dmit)2 Salts with Me3N+-TEMPO or TTF-(HO)TEMPO”, Mol. Cryst. Liq. Cryst., Vol. 380, pp. 263-268, 2002. International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2000), Honolulu, Hawaii, USA (Dec. 11-14, 2000).
  47. Y. Nishio, S. Sasaki, Y. Mori, K. Kajita, S. Aonuma, H. Sawa, M. Tamura, R. Kato, “Deuterium Freedom and M-I transition in (DMe-DCNQI)2Cu system”, Synth. Met., Vol. 133-134, pp. 569-571, 2003. Proceedings of the Yamada Conference LVI. The Fourth International Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets (ISCOM 2001), Rusutsu, Japan (Sep. 10-14, 2001).
  48. S. Aonuma, E. Fujiwara, T. Kanzawa and Y. Hosokoshi, “Synthesis, Properties and Molecular-Orbital Calculations of New -Acceptors as ortho-Analogues of DCNQI”, J. Phys.: Conf. Ser., Vol. 132, 012027 (7pp), 2008, the International Symposium on Molecular Conductors 2008 (ISMC2008), Okazaki, Japan (Jul. 23-25, 2008)


  • Conference Activities & Talks
  1. S. Aonuma and E. Fujiwara, “Synthesis and Properties of Ortho-Analogue of DCNQI,” International Symposium on Molecular Conductors 2008 (2008年7月・岡崎)
  2. S. Aonuma and Y. Hosokoshi, “Ammonium Ions with Organic Nitroxide Radical as Counter Cations of Acceptor-Based Molecular Conductors”, the 11th International Conference on Molecule-based Magnets (ICMM2008) (2008年9月・フィレンツェ)
  3. S. Aonuma, Y. Kamada, S. Nishihara and Y. Hosokoshi, “Magnetic and/or Conducting Complexes with -Acceptor Ligands DCNQIs and ortho-Analogues DCNAs”, The 8th International Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets (ISCOM 2009), PS3 (2009年9月・ニセコ)
  4. S. Aonuma, Y. Kamada and M. Araki, “Synthesis and Properties of New -Acceptors: Halogenated N,N’-dicyanoacenaphthoquinodiimines”, International Conference on Science and Technology of Synthetic Metals 2010 (ICSM 2010) (2010年7月・京都)
  5. 青沼秀児, 荒木将茂, 鎌田吉拡, 佐藤正春, “キノイド系有機π共役分子を用いた有機二次電池の作製とその電池特性”, 第51回電池討論会, 3G21 (2010年11月・名古屋)
  6. 青沼秀児，荒木将茂，佐藤正春, “テトラケトピラセン系正極活物質を用いた有機二次電池の充放電特性”, 第52回電池討論会, 4E01 (2011年10月・東京)
    他 232件


  • External funds, patents, copyrights, etc.
  1. 文部省科学研究費 一般研究(B), 二次元電子構造を持つ有機超伝導体開発のための分子設計, 1991年度～1993年度, 分担 (代表 加藤礼三)
  2. 文部省科学研究費 重点領域研究, 分子性錯体系における、スピンと伝導電子との相互作用に関する研究, 1992年度～1992年度, 分担 (代表 加藤礼三)
  3. 文部省科学研究費 奨励研究(A), 有機超伝導体を目指した非対称型有機ドナーの合成, 1993年度～1994年度, 代表, 1,000千円
  4. 文部省科学研究費 一般研究(C), 非平面的な炭素骨格を持つ有機伝導体の開発とその電子構造に関する研究, 1994年度, 代表, 2,000千円
  5. 文部省科学研究費 基盤研究(C)一般, 有機伝導体におけるπ－d相互作用に関する研究, 1997年度～1998年度, 代表, 2,300千円
  6. 文部科学省科学研究費 特定領域研究, 新規DCNQI類縁体の開発, 2004年度～2005年度, 代表, 4,400千円
  7. 文部科学省科学研究費 特定領域研究, 新奇分子性導体をめざしたテトラアザフルバレン系アクセプター分子の設計と合成, 2006年度～2007年度, 代表, 3,900千円
  8. 経済産業省 戦略的基盤技術高度化支援事業, モバイルディスプレイの高機能化に資する高効率な有機二次電池用正極活物質の開発, 再委託 (事業管理機関 大阪府立大学, 法認定事業者 株式会社ナード研究所)
  9. 佐藤、青沼 「電極活物質、電極、及び二次電池」WO2012121146


  • Activities in academic societies

青沼 秀児（あおぬま しゅうじ）AONUMA Shuji

  • Department
    工学部 環境科学科 准教授
    大学院 工学研究科 先端理工学専攻 准教授
  • Contribution in the local community


  • Committee members, officers, etc. in public institutions
  1. 文部科学省 科学研究費新学術領域研究専門委員会委員(新分子物質科学), 平成21年度, 23年度


  • Organization management such as academic societies


  • Disaster relief activities in Japan and overseas


  • Other

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